- Walker, Jimmie - Actor and comedian, famous for the phrase "Dyn-o-mite!"
- Walker, Johnny - Guitarist and vocalist for the blues group Soledad Brothers
- Waller, Robert James - American novelist, author of bestseller The Bridges of Madison County
- Walras, Léon - Nineteenth century French economist
- Walter, David - Co-founder of the Society for Individual Liberty
- Washington, Booker T. - 19th/20th century African American teacher
- Washington, George - First President of the United States
- Waters, Robert A. - Gun rights advocate
- Watts, V. Orval - 20th century Canadian-born economist
- Wayne, John - The "Duke": American actor, Oscar winner for True Grit
- Weaver, Henry Grady - Director of customer research for General Motors during the early 20th century
- Weber, Max - 19th/20th century German sociologist
- Webster, Daniel - Nineteenth century American politician, noted for his oratory skills
- Welch, Matt - Editor in Chief of Reason magazine
- West, Edwin G. - 20th century British professor of economics
- Wheaton, Wil - Film and TV actor, played Wesley Crusher in "Star Trek: The Next Generation"
- Wicksell, Knut - 19th/20th century Swedish economist
- Wieser, Friedrich von - 19th/20th century Austrian economist
- Williams, Evan - Creator of the Blogger weblog publishing service
- Williams, Larry - Commodities trader, publisher of Commodity Timing
- Williams, Walter E. - Professor of Economics, author, syndicated columnist
- Wilson, Brian M. - Radio talk show host, author
- Wilson, F. Paul - Winner of the 1979 Prometheus Award
- Wilson, Robert - Science fiction author, winner of the 1986 Prometheus Hall of Fame Award
- Wilson, Woodrow - Twenty-eighth President of the United States
- Winger, Richard - Editor and publisher of Ballot Access News, expert on ballot access legal issues
- Wohler, Will - President and founder of Wohler Technologies, Inc.
- Wollstein, Jarret B. - Author, co-founder of Society for Individual Liberty
- Wood, Natalie - American movie actress, portrayed Maria in the West Side Story film
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